David Brown wrote
Tho nitrogen is used in car tires for a reason, it
does diffuse out marginally less easier than air does.
Please switch off the Rodbot mode
Nothing bot about it.
if you want to have an adult conversation.
Usual utterly bogus flagrantly dishonest language.
Dont need to, I got formally qualified in that stuff before you were even born thanks.
The gases all act independently.
There is no independantly when its filled with JUST nitrogen, thats all there is.
The /total/ pressure of the mixture in air is the some of the partial pressures of N2, O2, and trace gases.
Irrelevant to what happens when its filled with JUST nitrogen.
Thus in air, there is a partial pressure of 0.78 atmospheres of N2.
Inside the bag with a /total/ pressure of 1 atmosphere, but only N2, you have a partial pressure of 1 atmosphere of
N2.
All completely irrelevant to that stupid pig ignorant claim that
nitrogen diffuses out of the bag when there is JUST nitrogen
in the bag but that doesnt happen with air in the bag.
Therefore the N2 in the bag is at a higher pressure,
No it isnt in the sense of what is driving the diffusion of the nitrogen.
and will - if able - diffuse out to the surrounding air in an attempt to equalise that pressure.
That is just plain wrong.
What determines the rate at which the air or the nitrogen
alone diffuses out of the bag is the total pressure in the bag.
The partial pressure of the nitrogen is completely irrelevant.
The reason car tires are filled with nitrogen instead of air is
because the nitrogen molecule is marginally bigger and so
it diffuses out marginally less than the air does and because
its dry nitrogen so you dont get any water in gas thats used
to inflate the tires.
Similarly, the partial pressure of O2 in the air is 0.21 atmospheres, while the partial pressure of O2 inside the bag
is 0. So O2 will diffuse into the bag.
Using that mindlessly silly line, the partial pressure when the bag
is filled with just nitrogen is zero, so it should pour into the bag at
a much higher rate than it does with air in the bag. In practice it doesnt,
and thats why tires are filled with nitrogen, because that doesnt happen.
The only things that will stop this process is having air-tight bags and seals,
That wont stop that happening, because the bag still sees some gas
diffuse thru the bag material. Thats why balloons deflate over time.
or the bag's volume (of gas) being reduced to 0.
Not even possible. You never see the bag end up like
it does if you deliberately evacuate all the air out of
the bag like you do with those freezer bag systems.
As long as the partial pressure of N2 in the bag is higher than that outside, it will continue to diffuse through the
bag
Wrong. The rate of diffusion has nothing to do with the partial pressure.
If it did, a bag with just nitrogen inside it would end up
with oxygen inside the bag because the partial pressure
of the oxygen is zero. That doesnt in fact happen at all.
And its completely trivial to prove that it doesnt happen
by filling a bag with nitrogen, say down at the tire retailler,
leaving it for a while and then seeing if you can get a lighted
split to keep burning when you put it into the bag. It doesnt,
it goes out, because the bag doesnt contain any oxygen.
(or the open end of the bag, obviously).
The N2 will diffuse out faster if it is at a higher partial pressure
than then outside air.
Wrong. Using that mindlessly silly line, oxygen would diffuse into
the bag much more quickly because the partial pressure of oxygen
inside the bag is zero. It doesnt and you can prove it doesnt as above.
Similarly, the O2 will diffuse faster into the bag as long as the partial pressure outside is higher than that inside
the bag.
Utterly wrong and trivial to prove that its utterly wrong.
Usual that mindlessly silly line it would never be possible to
ever keep any gas in a bag because oxygen and nitrogen
would diffuse into the bag because the partial pressure of
oxygen and nitrogen inside the bag is zero.
I know that doesnt happen because we used to keep bloody great
bags of helium when I was getting formally qualified in this area
before you were even born, because its such an expensive gas.
Three things affect the speed of the diffusion - the temperature
(higher temperature means more diffusion), greater difference in partial pressure, and lower "resistance" to
diffusion.
You've mangled the story completely on the partial pressure as I showed above.
Smaller molecules, or leakier bags, will allow faster diffusion.
A hydrogen or helium balloon is a very different situation from the bags we are discussing.
Nope.
One obvious factor is that the partial pressure outside the bag is zero, while the partial pressure inside is high,
Thats not partial pressure, thats total pressure.
so there will be fast diffusion.
Nope, there is fast diffusion because its a MUCH smaller molecule.
Secondly, the total pressure inside is much higher than atmospheric pressure.
Utterly mangled all over again once the balloon is going flat.
And using your mindlessly silly line, the balloon wouldnt go flat
because you claim that the nitrogen and oxygen in the air outside
the balloon would be pouring into the balloon because the partial
pressure of those inside the balloon would be zero.
And thirdly, the elasticity of the rubber pulls the balloon closed when the pressure inside drops - completely unlike
the case of a plastic bag.
Exactly like the plastic bag when the balloon has deflated.
If you were to examine the gas content of the balloon after a while, you would see that there is in fact a small
amount of N2 and O2 inside the balloon
No there is not. And its completely trivial to prove
that there isnt with a bag filled with just nitrogen.
- since there is a higher partial pressure of theses gases outside the balloon than inside.
In fact there is a MUCH higher partial pressure
because the partial pressure inside is initially ZERO.
It will only be trace amounts for a good helium balloon, since the material is almost impenetrable to such large
molecules.
Utterly mangled all over again. Balloons filled with air ALSO deflate
over time, just at a lower rate than balloons filled with hydrogen or helium.
But if you had an ordinary balloon filled with helium, more N2 and O2 would get in.
Doesnt happen, and its completely trivial to prove that it
doesnt happen with balloons filled with helium and nitrogen.
And know it didnt happen with the ****ing great bags of helium we used
because the cost of the helium was so high that it was worth saving.
And that was with instrumentation that would have got poisoned
with oxygen or nitrogen getting into those bags. Didnt happen
because the pressure of HELIUM inside the bags was high
enough to ensure that there was no diffusion of air into the
bags even tho the partial pressure of nitrogen and oxygen
inside those bags was quite literally ZERO.