Sure, but from where?
From the Main database folder, select the report and then right-click
and select Print.
Or
select the report and click Ctrl + P
Or
select the report and click on the Print tool button
Or
select the report, then click File + Print
Or
Code a command button click event:
DoCmd.OpenReport "ReportName"
Or
Code a command button click event:
DoCmd.SelectObject acReport, "ReportName", True
DoCmd.PrintOut acPrintAll