If you want a specific Excel file to open when you open excel
application, then goto:
The path to Startup folder would similar to this:
C:\```Application Data\Microsoft\Excel\XLSTART
Windows Explorer, move the icon of the workbook you want to open to an
alternate startup folder.
If you want to keep the workbook in its current location, use the
Create Shortcut command on the File menu to create a shortcut to the
workbook, and then move the shortcut to an alternate startup folder.
Now, restart Excel.
Otherwise, if you want to change the program that starts when you open
a file, goto:
My Computer or Windows Explorer, click the Tools menu, click Folder
Options, and then click the File Types tab. In the Registered file
types list, click the file type you want to open with a different
program, and then click Change. In the Open With dialog box, select
the program you want to use, and then click OK. Click OK in the Folder
Options dialog box.
I hope this helps...
Selva V Pasupathy
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Reference: Excel Help files.