Click Start Orb, All Programs, right click on the Windows Mail entry at the top
of the All Programs list and select Copy.
Right click on the Start Orb and select Explore All Users, scroll down to the
Startup folder and click on it, it the right hand window of the Startup folder,
right click and select Paste and approve the UAC prompt. A copy of the Windows
Mail shortcut should be pasted into the Startup folder.
To verify, click on Start Orb, All Programs, Scroll down to the Startup entry,
click it and you should see that Windows Mail has been added to your startup
programs.