if it's a shortcut that you want on your desktop here's a simple way to do it:
Go to <START>
Go to <MICROSOFT OUTLOOK 200*>
Right click on <MICROSOFT OUTLOOK 200*>
Go to <SEND TO..>
Go to <DESKTOP (CREAT SHORTCUT)
I think what you are asking is how to start Outlook when Windows starts.
In the Start/Programs find the Startup folder, now find Outlook and Right
click on Outlook and drag into the Startup folder, create a shortcut when it
asks you (I'm in Vista right now so this is from memory) and you should be
set to go.