Try using the Advance Filter
Select a cell in the database.
From the Data menu, choose Filter, Advanced Filter.
(In Excel 2007, click the Data tab on the Ribbon, then click Advanced
Filter.)
Choose 'Copy to another location'.
For the List range, select the column(s) from which you want to extract the
unique values.
Leave the Criteria Range blank.
Select a starting cell for the Copy to location.
Add a check mark to the Unique records only box.
Click OK.
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cheers, francis