Hey. The motherboard should detect it automatically at that speed, if the processor your using is meant to be run at a core FSB (front side bus) of 200.
If not, (this is overclocking), go into your BIOS (press delete during the disk detection at startup), go into the section for FSB ratio (or something similar) and check to see what it`s set to.
The FSB (front side bus) of your processor has to be 400Mhz (200Mhz double pumped if AMD Barton core) or more for PC3200 memory to run at 400Mhz.
To check this, download a program called CPU-Z which can be found here , and run it. It will tell you all about your memory, motherboard and processor.
Heres a screenie of what you should be looking for, my memory is PC2700 (333mhz) thats why it says 166Mhz because you have to times it by 2 (hence DDR- Double Date Rate). So if your memorys running at 400mhz it will read at 200 on the CPU-Z memory screen.