There could be few reasons for this. Check your bios to make sure that the
settings for waking up PC are set in such a way as to not to wake up your
PC. These settings include "wake up on LAN", "wake up on Modem ring","wake
up at specified time" or "wake up on loss of power". Also, check to see if
perhaps you also have the "wake up on key press" or "wake up on mouse" and
if so, it's possible that defective keyboard and/or very sensitive mouse
could also trigger such event with out any user action.
Since you say that this happens when you place your PC in Hibernate then
this rules out any background scheduled tasks. Defective components can also
cause such situation. In addition, to rule out corrupted CMOS, reset it by
pulling the CMOS battery (or use Clear Cmos jumper if present on your
motherboard)