Possibly you mean that the other computer is configured to automatically
show pictures when a picture CD is inserted.
Try going to 'My Computer', right-clicking on your CD-ROM drive and select
properties. Click the 'AutoPlay' tab at the top. From the drop-down box,
select 'Pictures'.
In the 'Actions' box, click 'Select an action to perform', then select 'View
a slideshow of the images' underneath.
Click ok.
Now try inserting the CD. Is this what you wanted?