Just like to know thanks, new case has space for two PSUS
Yes, they need have a common ground (usually provided by their
metal cases being fastened to metal computer case, but in some it
could require connecting ground lead from each) and connecting
PS-On wires together. This causes motherboard to 'sink more
current but generally it's not a problem, but if you wanted a
technically correct way of doing it then you'd want a low-ohm
resistor in series on the PS-On line after the two connect,
before it reaches the motherboard.
Primary question is how you want/need the rails, amperage
distributed. Easiest is using 2nd to power drives, fans, other
aux devices, but there "could" be a potential problem:
If your motherboard uses 5V for CPU and uses a weighted average
of 5V + 12V rail voltage to regulate, you might find the PSU
connected to mobo (having high 5V load but very low 12V load) has
a voltage level low on the 5V rail but high on 12V rail. In such
cases you might power other additional 12V components from psu
connected to motherboard.
This does not allow for current sharing per connected device or
hot-swapping.