You mean sent to those folders on your mail server? Only if you use IMAP.
POP3 accounts only check the inbox - it's a limitation of POP3, not Outlook.
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Diane Poremsky [MVP - Outlook]
Author, Teach Yourself Outlook 2003 in 24 Hours
Coauthor, OneNote 2003 for Windows (Visual QuickStart Guide)
Author, Google and Other Search Engines (Visual QuickStart Guide)